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- W2080049106 abstract "Nucleophilic aromatic radiofluorinations with [18F]fluoride in a microwave field were investigated in activated, partially deactivated and deactivated aromatic compounds. A coaxial resonance microwave cavity was used to produce a well-defined electromagnetic field in the samples. The leaving group on the aromatic rings as well as the ortho, meta and para orientation of electron-withdrawing and electron-donating substituents were varied. Yields comparable to or better than those reported for thermal treatments were obtained in very short reaction times (≤0.5 min, i.e. 120th–140th the thermal times) with very low microwave intensity and followed the trend of reactivity expected from the substrates activation for nucleophilic substitution." @default.
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- W2080049106 title "Fast chemistry in microwave fields: Nucleophilic 18F-radiofluorinations of aromatic molecules" @default.
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- W2080049106 doi "https://doi.org/10.1016/0969-8043(93)90033-7" @default.
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