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• W2080098075 abstract "The reaction of vapor-phase alkyl isocyanates (OCN−(CH2)n-1CH3) with OH-terminated alkanethiol template monolayers on Au produces well-organized self-assembled monolayers, containing intrachain carbamate linkages (Au/S(CH2)16O(CO)NH(CH2)n-1CH3, where n = 1−8, 11, and 12). X-ray photoelectron spectroscopy, contact angle goniometry, and reflection absorption infrared spectroscopy suggest that the template surface completely reacts with the isocyanates yielding a monolayer that contains an interchain hydrogen-bonded carbamate network. Spectroscopic data indicates that the alkyl underlayer remains well ordered following reaction with the isocyanates. The order of the overlayer and the hydrogen-bonding interactions between adjacent chains increase as a function of the alkyl isocyanate chain length, n. The overlayer appears to be well ordered for n ≥ 5." @default.
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• W2080098075 date "2004-03-02" @default.
• W2080098075 modified "2023-10-13" @default.
• W2080098075 title "Well-Ordered Self-Assembled Monolayers Created via Vapor-Phase Reactions on a Monolayer Template" @default.
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• W2080098075 doi "https://doi.org/10.1021/la0499620" @default.
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