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- W2080102014 abstract "Dimethyltitanocene, in conjunction with a wide variety of compounds containing Si-H bonds, is an excellent catalyst for the polymerization of acetylene to give free standing films. Polymerizations of acetylene in a variety of siloxane and silane matrices using this catalyst system are described. The polyacetylenes produced with a [(Me-SiHO-) 3 -(Me 2 Si) 17 -] n random copolymer showed very similar properties to those previously produced by Naarman et al. with a Shirakawa-type catalyst in a polydimethylsiloxane matrix. Ring, or chain, poly(methylhydrosiloxanes) with higher proportions of -(MeSiHO)- undergo redistribution in the course of acetylene polymerization to give polyacetylene embedded in an insoluble polysiloxane glass" @default.
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- W2080102014 date "1994-12-01" @default.
- W2080102014 modified "2023-09-25" @default.
- W2080102014 title "A novel catalyst system for the production of polyacetylene and of blends of polyacetylene with some silicon-containing polymers" @default.
- W2080102014 doi "https://doi.org/10.1002/pola.1994.080321619" @default.
- W2080102014 hasPublicationYear "1994" @default.
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