Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080110316> ?p ?o ?g. }
- W2080110316 endingPage "322" @default.
- W2080110316 startingPage "317" @default.
- W2080110316 abstract "The combination of the Passerini reaction and olefin cross‐metathesis is shown to be a very useful approach for the divergent synthesis of dendrimers. Castor oil‐derived platform chemicals, such as 10‐undecenoic acid and 10‐undecenal, are reacted in a Passerini reaction with an unsaturated isocyanide to obtain a core unit having three terminal double bonds. Subsequent olefin cross‐metathesis with tert ‐butyl acrylate, followed by hydrogenation of the double bonds and hydrolysis of the tert ‐butyl ester, leads to an active core unit bearing three carboxylic acid groups as reactive sites. Iterative steps of the Passerini reaction with 10‐undecenal and 10‐isocyanodec‐1‐ene for branching, and olefin cross‐metathesis with tert ‐butyl acrylate, followed by hydrogenation and hydrolysis allow the synthesis of a third‐generation dendrimer. All steps of the synthesis are carefully characterized by NMR, GPC, MS, and IR. image" @default.
- W2080110316 created "2016-06-24" @default.
- W2080110316 creator A5017781911 @default.
- W2080110316 creator A5042982696 @default.
- W2080110316 creator A5043292364 @default.
- W2080110316 creator A5069108788 @default.
- W2080110316 date "2013-12-06" @default.
- W2080110316 modified "2023-10-16" @default.
- W2080110316 title "Divergent Dendrimer Synthesis via the Passerini Three-Component Reaction and Olefin Cross-Metathesis" @default.
- W2080110316 cites W1557012298 @default.
- W2080110316 cites W1673626407 @default.
- W2080110316 cites W1963588879 @default.
- W2080110316 cites W1965923460 @default.
- W2080110316 cites W1971683346 @default.
- W2080110316 cites W1976304058 @default.
- W2080110316 cites W1979681733 @default.
- W2080110316 cites W1980482262 @default.
- W2080110316 cites W1986128136 @default.
- W2080110316 cites W1988564797 @default.
- W2080110316 cites W1992167318 @default.
- W2080110316 cites W2006183669 @default.
- W2080110316 cites W2006682004 @default.
- W2080110316 cites W2009500363 @default.
- W2080110316 cites W2013339223 @default.
- W2080110316 cites W2013436288 @default.
- W2080110316 cites W2017681223 @default.
- W2080110316 cites W2019086227 @default.
- W2080110316 cites W2022549879 @default.
- W2080110316 cites W2022650937 @default.
- W2080110316 cites W2023270917 @default.
- W2080110316 cites W2024285969 @default.
- W2080110316 cites W2025164491 @default.
- W2080110316 cites W2027289641 @default.
- W2080110316 cites W2029038878 @default.
- W2080110316 cites W2034067379 @default.
- W2080110316 cites W2040436974 @default.
- W2080110316 cites W2044525084 @default.
- W2080110316 cites W2045165089 @default.
- W2080110316 cites W2046797660 @default.
- W2080110316 cites W2048086925 @default.
- W2080110316 cites W2049160171 @default.
- W2080110316 cites W2051330683 @default.
- W2080110316 cites W2062656300 @default.
- W2080110316 cites W2072192656 @default.
- W2080110316 cites W2073296825 @default.
- W2080110316 cites W2074232728 @default.
- W2080110316 cites W2081132856 @default.
- W2080110316 cites W2087771960 @default.
- W2080110316 cites W2088532287 @default.
- W2080110316 cites W2093569543 @default.
- W2080110316 cites W2105475419 @default.
- W2080110316 cites W2115016322 @default.
- W2080110316 cites W2115038320 @default.
- W2080110316 cites W2119148015 @default.
- W2080110316 cites W2119525768 @default.
- W2080110316 cites W2140221090 @default.
- W2080110316 cites W2141492940 @default.
- W2080110316 cites W2147141426 @default.
- W2080110316 cites W2147409350 @default.
- W2080110316 cites W2152181273 @default.
- W2080110316 cites W2156460196 @default.
- W2080110316 cites W2162365515 @default.
- W2080110316 cites W2165571808 @default.
- W2080110316 cites W2166227770 @default.
- W2080110316 cites W2167509323 @default.
- W2080110316 cites W2168206768 @default.
- W2080110316 cites W2313458135 @default.
- W2080110316 cites W2313851648 @default.
- W2080110316 cites W2316982761 @default.
- W2080110316 cites W2323118711 @default.
- W2080110316 cites W2342444995 @default.
- W2080110316 cites W2498536911 @default.
- W2080110316 cites W4230066103 @default.
- W2080110316 cites W4233180878 @default.
- W2080110316 cites W4243421463 @default.
- W2080110316 cites W4252743587 @default.
- W2080110316 doi "https://doi.org/10.1002/marc.201300779" @default.
- W2080110316 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24356926" @default.
- W2080110316 hasPublicationYear "2013" @default.
- W2080110316 type Work @default.
- W2080110316 sameAs 2080110316 @default.
- W2080110316 citedByCount "40" @default.
- W2080110316 countsByYear W20801103162014 @default.
- W2080110316 countsByYear W20801103162015 @default.
- W2080110316 countsByYear W20801103162016 @default.
- W2080110316 countsByYear W20801103162017 @default.
- W2080110316 countsByYear W20801103162018 @default.
- W2080110316 countsByYear W20801103162019 @default.
- W2080110316 countsByYear W20801103162020 @default.
- W2080110316 countsByYear W20801103162021 @default.
- W2080110316 countsByYear W20801103162022 @default.
- W2080110316 crossrefType "journal-article" @default.
- W2080110316 hasAuthorship W2080110316A5017781911 @default.
- W2080110316 hasAuthorship W2080110316A5042982696 @default.
- W2080110316 hasAuthorship W2080110316A5043292364 @default.
- W2080110316 hasAuthorship W2080110316A5069108788 @default.
- W2080110316 hasConcept C153914509 @default.
- W2080110316 hasConcept C15920480 @default.