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- W2080135260 abstract "High sulfide conversion and predominant sulfoxide yield has been observed with 0.1% vanadium doped disordered mesoporous Ti1−xVxO2 material at ambient and sub ambient temperatures using environmentally green H2O2 oxidant. Ti1−xVxO2 materials were prepared by one-pot solution combustion method in less than 15 min and thoroughly characterized by X-ray diffraction, HRTEM, Raman spectra and other physicochemical techniques. Different sulfides, such as, phenylsulfide, methyl-p-tolylsulfide, ethylsulfide, thioanisole, were converted into the corresponding sulfoxide. Isolated V5+ incorporated in the TiO2 lattice is likely to be the active species for the sulfide oxidation reaction. Catalyst recycling studies indicates the robustness of the catalyst." @default.
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- W2080135260 date "2013-02-01" @default.
- W2080135260 modified "2023-10-01" @default.
- W2080135260 title "Disordered mesoporous V/TiO2 system for ambient oxidation of sulfides to sulfoxides" @default.
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- W2080135260 doi "https://doi.org/10.1016/j.apcata.2012.11.035" @default.
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