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- W2080135902 abstract "A potassium- and copper-promoted iron Fischer-Tropsch (F-T) catalyst was studied by X-ray photoelectron spectroscopy, Auger spectroscopy and ion scattering spectrometry to determine the changes in surface speciation of iron and carbon, and the distribution of potassium and copper on exposure to various pretreatment conditions. A transformation in surface composition from Fe2O3 to Fe3O4 to iron carbide was enhanced by pretreating catalysts with hydrogen-carbon monoxide compared with carbon monoxide and retarded by the addition of water vapor to the gases. A lower initial F-T activity observed for hydrogen-carbon monoxide-compared with carbon monoxide-pretreated catalysts, may be explained by greater coverage of the “active” carbide species by surface carbonaceous material formed during pretreatment." @default.
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- W2080135902 date "1989-03-01" @default.
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- W2080135902 title "Effects of pretreatment on the surface properties of iron fischer—tropsch catalysts" @default.
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- W2080135902 doi "https://doi.org/10.1016/s0166-9834(00)80276-6" @default.
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