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- W2080143401 abstract "Reactions of the precursors [Ni(macrocyclic ligand)]2+ with [W(CN)8]3− afford two octacyanotungstate-based assemblies, (H2L1)0.5[Ni(L1)][W(CN)8]·2DMF·H2O (L1 = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) (1) and [Ni(L2)]3[W(CN)8]2·4H2O (L2 = 3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane) (2). Single crystal X-ray diffraction shows that 1 consists of anionic one-dimensional (1D) linear chains, while 2 is built of 2D graphite-like layers with (6, 3) topology. Magnetic studies reveal that both complexes exhibit metamagnetic behavior from the spin-canted antiferromagnet to the ferromagnet induced by field." @default.
- W2080143401 created "2016-06-24" @default.
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- W2080143401 date "2011-01-01" @default.
- W2080143401 modified "2023-09-25" @default.
- W2080143401 title "Two octacyanometallate-based Ni(ii)W(v) bimetallic assemblies with metamagnetism" @default.
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- W2080143401 doi "https://doi.org/10.1039/c0dt01773f" @default.
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