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- W2080159516 abstract "The results of an infrared diode-laser-heterodyne investigation of the ν5 band of deuterated fluoroform (CDF3) are presented. Infrared heterodyne measurements (410), together with the previously obtained 88 infrared laser-Stark measurements, 12 infrared-radiofrequency, two-photon measurements, 8 microwave measurements, and 22 submillimeter-wave heterodyne measurements were analyzed by linear least-squares fitting of the data with a 43-constant linear Hamiltonian. Most of the ground-state and ν5-state constants are obtained to very high accuracy, and the fit to the data is excellent. Examination of the data reveals effects such as A+-A− splittings and perturbation-allowed transitions arising from the mixing of kl = 1 and kl = −2 levels in the ν5 state due to (±2, ±1) interactions." @default.
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- W2080159516 date "1984-08-01" @default.
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- W2080159516 title "The ν5 perpendicular band of deuterated fluoroform" @default.
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- W2080159516 doi "https://doi.org/10.1016/0022-2852(84)90158-9" @default.
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