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• W2080172940 abstract "The conventional (non-polarized) and linear-polarized IR-spectra of 2-pyrrolidone and laurolactam as typical representatives of lactams with cis- and trans-amide configuration, respectively, were studied by means of difference IR-spectroscopy. The application of this method to treatment of the non-polarized IR-spectra permits additional conclusions about the likely self-associates of these compounds dissolved in aprotic solvents. By means of the difference linear-dichroic IR-spectroscopy, a more precise assignment of the characteristic bands of the lactam cis- and trans-peptide forms as well as their stereo structures were accomplished. A comparative analysis with the linear-dichroic IR-spectra of ɛ-caprolactam and caprylolactam, as similar compounds, with cis- and trans-conformation, respectively, was also carried out." @default.
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• W2080172940 date "2006-02-01" @default.
• W2080172940 modified "2023-09-26" @default.
• W2080172940 title "Reducing-difference infrared spectral analysis of cis- and trans-configurated lactams" @default.
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• W2080172940 doi "https://doi.org/10.1016/j.saa.2005.05.035" @default.
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