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- W2080180652 abstract "Abstract A series of experiments with the trimethyl-, triethyl-, tri-n-butyl-, tri-n-decyl- and tri-p-tolylchromium systems with various terminal olefins, internal olefins and 1,5-cyclooctadiene under a variety of conditions have been carried out. The results indicate that the activity of the catalyst (probably a hydrido-chromium species) and the rate of isomerization of added olefin are temperature dependent. The consistent isomerization of terminal olefins to trans- and cis-2-olefins as major product and of 1,5-cyclooctadiene to the 1,4- then the 1,3-diene is in keeping with a mechanism involving the cis-addition/elimination of a metal hydride species." @default.
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- W2080180652 date "1968-08-01" @default.
- W2080180652 modified "2023-09-25" @default.
- W2080180652 title "Alkyltransition metal compounds II. n-alkylchromium systems: olefin isomerization" @default.
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- W2080180652 doi "https://doi.org/10.1016/s0022-328x(00)82767-9" @default.
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