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- W2080185251 abstract "Hydrolysis studies of derivatives of molybdocene dichloride in which the two chloride ligands were replaced by 3,5-bis(trifluoromethyl)thiophenol, 3,5-bis(trifluoromethyl)benzyl thiol, and 2,2,2-trifluoroethane thiol ligands confirmed that the electron-withdrawing groups affect the lability of the Mo−S bonds and promote slow generation of the putative biologically active species “Cp2Mo2+”; the trifluoroethane thiol derivative underwent 50% hydrolysis in 14 h in 10% D2O/DMSO-d6. The structure of molybdocene bis(S-3,5-bis(trifluoromethyl)benzyl thiol) was confirmed by X-ray crystal structure analysis." @default.
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- W2080185251 date "2006-05-28" @default.
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- W2080185251 title "Synthesis and Hydrolysis of Thiol Derivatives of Molybdocene Dichloride Incorporating Electron-Withdrawing Substituents" @default.
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- W2080185251 doi "https://doi.org/10.1021/om060133e" @default.
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