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- W2080196391 abstract "The rhodium(I)-catalyzed reaction of alkynes with 2-bromophenylboronic acids in the presence of paraformaldehyde resulted in a CO gas-free carbonylative cyclization, yielding indenone derivatives. [RhCl(BINAP)]2 and [RhCl(cod)]2 were responsible for the decarbonylation of formaldehyde and the subsequent carbonylation of alkynes with 2-haloboronic acids, respectively, leading to efficient whole carbonylation. Sterically bulky and electron-withdrawing groups on unsymmetrically substituted alkynes favored the α-position of indenones." @default.
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- W2080196391 date "2009-09-01" @default.
- W2080196391 modified "2023-09-25" @default.
- W2080196391 title "ChemInform Abstract: Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde." @default.
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- W2080196391 doi "https://doi.org/10.1002/chin.200935103" @default.
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