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- W2080196872 abstract "Abstract A study has been made of the onset of chloride deprivation on the oxygen-evolving characteristics of isolated spinach chloroplasts. Using a modulated oxygen electrode it is found that the type of inhibition depends on the anion replacing chloride in the bathing medium. With nitrate a large increase in phase lag accompanies a relatively small inhibition which can be shown to be consistent with a decrease in the rate constant of the reaction which limits the rate of electron transport between water and Photosystem II. With sulphate there is a very small phase change but a larger inhibition which suggests that replacing chloride with sulphate in an electron-transport chain shuts off that chain. With acetate there is a moderate increase in phase lag and the largest inhibitory effect. The phase-lag increase suggests that acetate is affecting the same chloride-sensitive site as nitrate. However, the inhibition cannot be explained by this effect alone and points to the existence of a second chloride-sensitive site. Of the four forward reactions associated with the Kok model of oxygen evolution (Kok, B., Forbush, B. and McGloin, M. (1970) Photochem. Photobiol. 11, 457–475) only S∗3 → S0 is slowed down when chloride is replaced by nitrate. This reaction is not slowed down by replacing chloride with sulphate." @default.
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- W2080196872 date "1984-02-01" @default.
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- W2080196872 title "The influence of anions on oxygen evolution by isolated spinach chloroplasts" @default.
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- W2080196872 doi "https://doi.org/10.1016/0005-2728(84)90034-3" @default.
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