FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080201044> ?p ?o ?g. }

• W2080201044 endingPage "516" @default.
• W2080201044 startingPage "506" @default.
• W2080201044 abstract "Abstract TiCl 4 (THF) 2 reacts with two equivalents of sodium in THF to afford the soluble TiCl 2 (THF)n (1), which has been characterized analytically and by spectroscopic and magnetic measurements. By redox reactions. TiCl 2 (THF) n gives TiCl 2 (9,10-C 10 H 8 O 2 ) (2), or TiCl 2 (benzoate) 2 .(3), with 9,10-phenanthrenequinone or dibenzoylperoxide in toluene, respectively. By operating in 1,2-dimethoxyethane (DME), Na(DME) 1.5 [TiCl 4 (DME)] (4), or NaTiCl 3 (DME) 2 have been isolated from the reaction of TiCl 4 (DME) with one or two equivalents of sodium, respectively. From 4, by cation exchange, PPN[TiCl 4 (DME)] [PPN = bis(triphenylphosphine)iminium] (5), has been obtained and characterized analytically, spectroscopically and by X-ray diffraction methods. Crystal data: C 40 HCl 4 NO 2 P 2 Ti. MW = 818.4, space group: Pna2 1 (N° 33). a = 14.445(2), b = 15.690(2), c = 17.544(2) Å . V = 3976(2) Å 3 , Z = 4, F(000) = 1692, R = 0.041, Rw = 0.0420. The titanium(III) atom in the anion has the expected cis-octahedral, slightly distorted, geometry. By reaction of TiBr 4 (DME) 0.5 with sodium in DME, TiBr 3 (DME) 1.5 .1.5 DM E (7), is the product. Bis(mesitylene)vanadium(0), Vmes 2 , reacts with two equivalents of CPh 3 Cl in DME, to give VCl 2 (DME) n ." @default.
• W2080201044 created "2016-06-24" @default.
• W2080201044 creator A5005009184 @default.
• W2080201044 creator A5041253819 @default.
• W2080201044 creator A5045953936 @default.
• W2080201044 creator A5050991363 @default.
• W2080201044 creator A5053942420 @default.
• W2080201044 creator A5062413478 @default.
• W2080201044 date "1996-04-01" @default.
• W2080201044 modified "2023-10-18" @default.
• W2080201044 title "New Preparative Methods for the Halides of Titanium(II) and Vanadium(II): Reduction of Titanium(IV) Halides with Sodium and Oxidation of Bis(mesitylene)vanadium(0)" @default.
• W2080201044 doi "https://doi.org/10.1515/znb-1996-0413" @default.
• W2080201044 hasPublicationYear "1996" @default.
• W2080201044 type Work @default.
• W2080201044 sameAs 2080201044 @default.
• W2080201044 citedByCount "17" @default.
• W2080201044 countsByYear W20802010442014 @default.
• W2080201044 countsByYear W20802010442015 @default.
• W2080201044 countsByYear W20802010442016 @default.
• W2080201044 countsByYear W20802010442020 @default.
• W2080201044 countsByYear W20802010442022 @default.
• W2080201044 crossrefType "journal-article" @default.
• W2080201044 hasAuthorship W2080201044A5005009184 @default.
• W2080201044 hasAuthorship W2080201044A5041253819 @default.
• W2080201044 hasAuthorship W2080201044A5045953936 @default.
• W2080201044 hasAuthorship W2080201044A5050991363 @default.
• W2080201044 hasAuthorship W2080201044A5053942420 @default.
• W2080201044 hasAuthorship W2080201044A5062413478 @default.
• W2080201044 hasBestOaLocation W20802010441 @default.
• W2080201044 hasConcept C115624301 @default.
• W2080201044 hasConcept C147789679 @default.
• W2080201044 hasConcept C155647269 @default.
• W2080201044 hasConcept C161790260 @default.
• W2080201044 hasConcept C171560689 @default.
• W2080201044 hasConcept C17525397 @default.
• W2080201044 hasConcept C178790620 @default.
• W2080201044 hasConcept C179104552 @default.
• W2080201044 hasConcept C185592680 @default.
• W2080201044 hasConcept C198819137 @default.
• W2080201044 hasConcept C2777247709 @default.
• W2080201044 hasConcept C2777352791 @default.
• W2080201044 hasConcept C2778142098 @default.
• W2080201044 hasConcept C2778734912 @default.
• W2080201044 hasConcept C504678139 @default.
• W2080201044 hasConcept C506065880 @default.
• W2080201044 hasConcept C537181965 @default.
• W2080201044 hasConcept C55904794 @default.
• W2080201044 hasConcept C68801617 @default.
• W2080201044 hasConcept C8010536 @default.
• W2080201044 hasConceptScore W2080201044C115624301 @default.
• W2080201044 hasConceptScore W2080201044C147789679 @default.
• W2080201044 hasConceptScore W2080201044C155647269 @default.
• W2080201044 hasConceptScore W2080201044C161790260 @default.
• W2080201044 hasConceptScore W2080201044C171560689 @default.
• W2080201044 hasConceptScore W2080201044C17525397 @default.
• W2080201044 hasConceptScore W2080201044C178790620 @default.
• W2080201044 hasConceptScore W2080201044C179104552 @default.
• W2080201044 hasConceptScore W2080201044C185592680 @default.
• W2080201044 hasConceptScore W2080201044C198819137 @default.
• W2080201044 hasConceptScore W2080201044C2777247709 @default.
• W2080201044 hasConceptScore W2080201044C2777352791 @default.
• W2080201044 hasConceptScore W2080201044C2778142098 @default.
• W2080201044 hasConceptScore W2080201044C2778734912 @default.
• W2080201044 hasConceptScore W2080201044C504678139 @default.
• W2080201044 hasConceptScore W2080201044C506065880 @default.
• W2080201044 hasConceptScore W2080201044C537181965 @default.
• W2080201044 hasConceptScore W2080201044C55904794 @default.
• W2080201044 hasConceptScore W2080201044C68801617 @default.
• W2080201044 hasConceptScore W2080201044C8010536 @default.
• W2080201044 hasIssue "4" @default.
• W2080201044 hasLocation W20802010441 @default.
• W2080201044 hasOpenAccess W2080201044 @default.
• W2080201044 hasPrimaryLocation W20802010441 @default.
• W2080201044 hasRelatedWork W1989807438 @default.
• W2080201044 hasRelatedWork W2012585432 @default.
• W2080201044 hasRelatedWork W2013430695 @default.
• W2080201044 hasRelatedWork W2036985840 @default.
• W2080201044 hasRelatedWork W2080855329 @default.
• W2080201044 hasRelatedWork W232511785 @default.
• W2080201044 hasRelatedWork W2366992789 @default.
• W2080201044 hasRelatedWork W2372900848 @default.
• W2080201044 hasRelatedWork W4313596886 @default.
• W2080201044 hasRelatedWork W55036528 @default.
• W2080201044 hasVolume "51" @default.
• W2080201044 isParatext "false" @default.
• W2080201044 isRetracted "false" @default.
• W2080201044 magId "2080201044" @default.
• W2080201044 workType "article" @default.