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- W2080205105 abstract "In the present work, thin films of ruthenium based metal–organic frameworks are synthesized using a layer-by-layer (LbL) technique and the film is characterized using XRD, FE-SEM, UV/visible spectroscopy, cyclic voltammetry and photoluminance spectroscopy. Further, the feasibility of the MOF film as a sensitizer in a solar cell is investigated. The HOMO–LUMO level of the frameworks is estimated and is found to be suitable to allow the use of the frameworks as a sensitizer for TiO2. When TiO2 mesoporous film is sensitized with the LBL thin film of the frameworks and a Grätzel type liquid junction solar cell is constructed, it demonstrates the cell performance of Isc = 2.56 mA cm−2, Voc = 0.63 V, FF = 0.63, and Eff = 1.22%. Photoluminescence spectroscopy and electrochemical impedance spectroscopy show that iodine doping into the frameworks is essential to facilitate the photogenerated electron transfer from the frameworks to TiO2." @default.
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- W2080205105 date "2014-01-01" @default.
- W2080205105 modified "2023-10-14" @default.
- W2080205105 title "Layer-by-layer deposition and photovoltaic property of Ru-based metal–organic frameworks" @default.
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- W2080205105 doi "https://doi.org/10.1039/c4ra00397g" @default.
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