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- W2080209596 abstract "The binary system Na 3 AlF 6 –Na 2 SO 4 has been investigated. A eutectic point was found at 91 mole % Na 2 SO 4 . On the Na 3 AlF 6 side of the diagram extensive solid solution was found. No solid solution was observed on the Na 2 SO 4 side, either by thermal analysis or by Debye–Scherrer diagrams. The freezing point depression of Na 2 SO 4 caused by additions of Na 3 AlF 6 has been used to evaluate the dissociation scheme of the cryolite anion in a sodium sulphate melt. The calculations favor the following scheme:AlF 6 3− = AlF 4 − + 2F − ." @default.
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- W2080209596 date "1959-07-01" @default.
- W2080209596 modified "2023-10-18" @default.
- W2080209596 title "THE PHASE DIAGRAM OF THE SYSTEM Na<sub>3</sub>AlF<sub>6</sub>–Na<sub>2</sub>SO<sub>4</sub> AND THE DISSOCIATION OF THE CRYOLITE ANION IN MOLTEN SODIUM SULPHATE" @default.
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- W2080209596 doi "https://doi.org/10.1139/v59-172" @default.
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