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- W2080227522 abstract "Abstract In the time-resolved flash photolysis of I 2 in O 3 , in addition to the IO electronic bands between 21500 and 26000 cm −1 , a new absorption spectrum has been observed between 15000 and 21500 cm −1 , which is attributed to the A-X electronic bands of the OIO radical. A number of spectroscopic constants of the A state of OIO were determined by linear least-squares fitting the observed spectrum: ν 1 (symmetric IO stretch) ω 1 = 631 cm −1 , ν 1 anharmonicity constant ω 1 χ 1 = 2.6 cm −1 , ν 2 (OIO angle bend) ω 2 = 177 cm −1 , electronic energy with respect to the ground state T e = 14553 cm −1 . These values are in good agreement with those expected from measurements of the same electronic bands in OClO and OBrO." @default.
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- W2080227522 date "1996-03-01" @default.
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- W2080227522 title "First observation of the OIO molecule by time-resolved flash photolysis absorption spectroscopy" @default.
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- W2080227522 doi "https://doi.org/10.1016/0009-2614(96)00114-5" @default.
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