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• W2080229241 abstract "The microlamellar and smectic liquid crystal (LC) structures of a block copolymer of a main-chain LC polyester connected at both ends with poly(ethyl methacrylate) are investigated by fiber X-ray scattering. In the as-spun fiber, the lamellae are parallel to the fiber axis, while the smectic layers are perpendicular to it. Annealing the as-spun fiber at a temperature higher than the isotropization temperature (Ti) of the LC segment preserves the lamellae, but the LC structure disappears. Further annealing the fiber at T < Ti improves the lamellar stacking coherence and aligns the smectic layers parallel to the lamellae. In contrast, annealing the as-spun fiber at T < Ti conserves the smectic layers and arranges the lamellae in parallel to the smectic layers. Thus, the liquid crystallinity affects the lamellar ordering and orientation." @default.
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• W2080229241 date "2013-08-02" @default.
• W2080229241 modified "2023-09-23" @default.
• W2080229241 title "Influence of Smectic Liquid Crystallinity on Lamellar Microdomain Structure in a Main-Chain Liquid Crystal Block Copolymer Fiber" @default.
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• W2080229241 doi "https://doi.org/10.1002/macp.201300353" @default.
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