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• W2080233656 endingPage "2703" @default.
• W2080233656 startingPage "2695" @default.
• W2080233656 abstract "meso-Phenyldipyrromethene acetylacetonato copper(II) complexes [Cu(dpm-C6H4R)(acac)] (dpm-C6H4R = phenyl-substituted dipyrromethene, acac = acetylacetonato) with different substituents R at the phenyl moiety were synthesized. These substituents determine the mode of assembly into polymeric chains, namely, via hydrogen bonds, coordinative bonds, or covalent bonds (by immobilization on a polymer). Although the primary coordination sphere around the copper center is essentially identical for all complexes reported in this study (square-planar geometry with N2O2 coordination), subtle differences due to the different microenvironments have been observed in their structures, properties, and reactivity as probed by IR spectroscopy, electron paramagnetic resonance spectroscopy, magnetic measurements, thermal analyses, density functional theory calculations, and reaction with pyridine." @default.
• W2080233656 created "2016-06-24" @default.
• W2080233656 creator A5011496890 @default.
• W2080233656 creator A5076657365 @default.
• W2080233656 date "2006-02-25" @default.
• W2080233656 modified "2023-09-23" @default.
• W2080233656 title "Heteroleptic Cu(II) Dipyrromethene Complexes Linked via Hydrogen Bonds, Coordinative Bonds, and Covalent Bonds: Probing the Coordination Environment by Electron Paramagnetic Resonance Spectroscopy" @default.
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• W2080233656 doi "https://doi.org/10.1021/ic0515047" @default.
• W2080233656 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16529493" @default.
• W2080233656 hasPublicationYear "2006" @default.
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