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- W2080257025 abstract "Abstract Reported are rates of CO substitution by L of M 4 (CO) 11 L(M = Co, Ir; L = PPh 3 , P n Bu 3 , P(OMe) 3 , P(OEt) 3 ) in the presence of added Me 3 NO. The rate law is the same as that found earlier on such reactions, being first-order in the concentrations of metal carbonyl and of Me 3 NO but zero-order in ligand concentration. The Ir compounds react from 2 to 7 times faster than do the corresponding Co compounds, and for each the rates of reaction with changes in ligand decrease in the order P(OMe) 3 > P(OEt) 3 > P n Bu 3 . The results are compared with earlier studies in the M 3 (CO) 12 and M 3 (CO) 11 L (M = Fe, Ru, Os) clusters, where it was found that the reactivities decrease in the order Fe > Ru > Os. That this order differs from that now reported (Co 4 (CO) 11 L clusters is discussed in terms of the presumed important contribution of CO bridging to the rates of associative reactions in metal carbonyl clusters." @default.
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- W2080257025 date "1991-10-01" @default.
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- W2080257025 title "Kinetics and mechamisms of CO substitution of M4(CO)11L(M = Co, Ir; L = PPh3 PnBu3, P(OMe)3, P(OEt)3) with L in the presence of the Me3NO" @default.
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- W2080257025 doi "https://doi.org/10.1016/0022-328x(91)80167-i" @default.
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