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• W2080270078 abstract "We report a high pressure Raman study of orthorhombic elemental sulfur from ambient pressure to ∼ 25 GPa. Using a near infrared laser and low laser intensity on the scattering volume, we achieve off-resonant conditions up to larger pressures in comparison with previous studies. Raman spectra were recorded over the full spectral range including external (librational, translational) and internal (bond bending and bond stretching) modes. Drastic changes are observed as regards the peak frequencies, relative intensities and band splitting of degenerate modes. The main outcome of the present study is the observation of a “structural” transition at ∼ 16 GPa manifested as slope changes of certain frequencies and sudden relative intensities changes. The present findings are discussed in the context of previous pressure Raman studies and comparison with existing X-ray diffraction as well as ab initio molecular dynamics results is attempted." @default.
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• W2080270078 date "2013-03-01" @default.
• W2080270078 modified "2023-10-16" @default.
• W2080270078 title "Elemental sulfur under high hydrostatic pressure. An up-to-date Raman study" @default.
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• W2080270078 doi "https://doi.org/10.1080/08957959.2012.760199" @default.
• W2080270078 hasPublicationYear "2013" @default.
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