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- W2080275315 abstract "A reductive rearrangement of aminocyclopropanes is described for the synthesis of cis- or trans-fused bicyclic 1,2-diaminocyclobutanes. Ionization of a cyclic aminal using BF3·OEt2 induces rearrangement to a cyclobutyl iminium ion, which is subsequently reduced by Et3SiH. Substitution with allyltrimethylsilane allows carbon incorporation, giving a quaternary center. Silyloxy-substituted cyclopropanes rearrange rapidly to cyclobutanones which react with NaBH4 to provide 1,2-aminohydroxycyclobutanes. These aminals were generated by the reduction of a Boc-imide with DIBAL-H or LiBH4." @default.
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- W2080275315 date "2008-02-01" @default.
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- W2080275315 title "An unexpected aminocyclopropane reductive rearrangement" @default.
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- W2080275315 doi "https://doi.org/10.1016/j.tetlet.2007.12.054" @default.
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