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• W2080275448 abstract "The literature results for the pyrolysis of bis trifluoromethyl peroxide are reexamined and compared with those for dimethyl peroxide. The thermochemistry yields the result that the π-bond energy in carbonyl fluoride is 96 ± 10 kcal/mol compared to 74 kcal/mol for that in formaldehyde. Thermodynamic additivity contributions are derived for the C(F)3(O) and O(C)(F) groups. Some conclusions are drawn in relation to the oxidation of halogeno methyl radicals and the chemistry of the atmosphere." @default.
• W2080275448 created "2016-06-24" @default.
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• W2080275448 date "1982-08-01" @default.
• W2080275448 modified "2023-09-26" @default.
• W2080275448 title "A reexamination of the pyrolysis of bis trifluoromethyl peroxide" @default.
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• W2080275448 doi "https://doi.org/10.1002/kin.550140812" @default.
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