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- W2080276143 abstract "The effect of boiling 5 M NaOH on the nature of poorly crystalline iron oxides in some iron pans from Scottish soils has been investigated by IR and Mössbauer spectroscopy in conjunction with XRD. In samples that contained goethite and other crystalline oxides there was substantial production of goethite from the less well-defined phases as a result of the alkali treatment. Neither kaolinite nor humic acid, when added to the samples, was effective in preventing this transformation, although some inhibition was observed. There was, however, no goethite production with a pan that had no crystalline iron oxides, although this could be stimulated by the addition of small amounts of either goethite or haematite. The practice of using the boiling alkali method routinely for the concentration of crystalline iron oxides in soils should, therefore, be considered carefully, since any co-existing crystalline and non-crystalline phases are likely to lead to the transformation of the latter to goethite." @default.
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- W2080276143 date "1988-03-01" @default.
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- W2080276143 title "Transformation of poorly-crystalline oxides during boiling with NaOH to concentrate iron oxides from soils" @default.
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- W2080276143 doi "https://doi.org/10.1111/j.1365-2389.1988.tb01197.x" @default.
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