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- W2080282113 abstract "Abstract In aqueous medium P4S10 reacts with sodium fluoride yielding sodium difluoropentathiodiphosphate, Na2[P2S5F2][1]. It was found that in acetonitrile sulfur-rich phosphorus sulfides (the S:P ratio varying from 11:4 to 16:4) react with fluoride under formation of alkali sulfane-α,ω-bis(fluorodithiophosphates) of the general formula 1 The higher the sulfur content of the sulfur-rich phosphorus sulfides the higher are the yields of sulfane derivatives. These sulfane-α,ω-bis(fluorodithiophosphates) are identified by 19 F and 31 P NMR spectroscopy. For the trisulfane derivative 2 long range couplings over six bonds are observed. These results may be explained by the assumption of a substitution of S-atoms in the P-S-P bridges of the adamantane-like P4S10 molecule by Sn-units in the sulfur-rich phosphorus sulfides. On the other side solutions of alkali pentathiodifluorodiphosphates in CH3CN react with sulfur also to a mixture of compounds of type 2 . Therefore the nucleophilic degradation of P4S10+m(m=1−5) with fluorides do not allow definite conclusions about the molecular structure of the starting compounds." @default.
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- W2080282113 date "1985-08-01" @default.
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- W2080282113 title "Salts of sulfane-α,ω-bis(fluorodithiophosphoric acids)" @default.
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- W2080282113 doi "https://doi.org/10.1016/s0022-1139(00)83305-9" @default.
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