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• W2080292757 startingPage "568" @default.
• W2080292757 abstract "A novel binuclear metallacyclic complex, [Cu(hfac)2(bpmu)]2, was isolated by reacting copper(II) hexafluoroacetylacetonate with the bpmu ligand. The crystal structure reveals the presence of dimetal units with the Cu(II) centers in a six-coordinate environment and bridged by the bpmu spacers. The crystal consists of a racemate with the two copper(II) ions of one dimer molecule carrying either a ΔΔ or ΛΛ configuration. The pyridyl-urea-based spacers are connected intramolecularly by the expected strong urea-based hydrogen bonds OC(N–H)2⋯OC. The same type of H-bonds allows the molecular units of the same chirality to assemble forming supramolecular columns. This conformationally defined array and hydrogen-bonding network, together with the bulky properties of the fragment {Cu(hfac)2}, were used as a pre-programmed supramolecular information for controlling the formation of discrete species." @default.
• W2080292757 created "2016-06-24" @default.
• W2080292757 creator A5030715383 @default.
• W2080292757 creator A5051936165 @default.
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• W2080292757 date "2005-06-01" @default.
• W2080292757 modified "2023-09-24" @default.
• W2080292757 title "Self-assembly of the cyclic dimer [Cu(hfac)2(bpmu)]2 (bpmu=N,N′-bis(3-pyridylmethyl)urea; hfac=hexafluoroacetylacetonate ion) using coordination chemistry and predictable OC(N–H)2⋯OC hydrogen bonds" @default.
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• W2080292757 doi "https://doi.org/10.1016/j.inoche.2005.03.018" @default.
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