FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080293453> ?p ?o ?g. }

• W2080293453 endingPage "144" @default.
• W2080293453 startingPage "133" @default.
• W2080293453 abstract "The reaction of tert-butylacetylene (t-BA) in the presence of seven-coordinate tungsten(II) and molybdenum(II) compounds [MCl(M′Cl3)(CO)3(NCR)2] (M=Mo, W; M′=Sn, Ge; R=Me, Et) leads to the catalytic coupling of t-BA molecules and the formation of high-molecular-weight (M̄n>105) soluble polymers. The geometric structure of poly(tert-butylacetylene) (P-t-BA) was determined by means of 1H- and 13C-NMR spectroscopy. The monitoring of the reaction between t-BA and the metal complex by means of 1H-NMR spectroscopy provided further insight into the initiation step of this polymerization process. The reaction of a heterobimetallic compound with a stoichiometric amount of t-BA yields compounds in which CO and/or nitrile ligands have been replaced by a t-BA ligand. The alkyne molybdenum(II) and tungsten(II) complexes formed were characterized structurally by means of IR and NMR spectroscopy. The possible mechanisms for the formation of very reactive intermediate compounds and their role in the catalytic process are discussed." @default.
• W2080293453 created "2016-06-24" @default.
• W2080293453 creator A5057431845 @default.
• W2080293453 creator A5060019697 @default.
• W2080293453 date "2000-10-01" @default.
• W2080293453 modified "2023-10-17" @default.
• W2080293453 title "Polymerization of tert-butylacetylene by seven-coordinate heterobimetallic tungsten(II) and molybdenum(II) compounds" @default.
• W2080293453 cites W1964423387 @default.
• W2080293453 cites W1966514289 @default.
• W2080293453 cites W1967123025 @default.
• W2080293453 cites W1972732694 @default.
• W2080293453 cites W1974280967 @default.
• W2080293453 cites W1977039970 @default.
• W2080293453 cites W1978478020 @default.
• W2080293453 cites W2005181552 @default.
• W2080293453 cites W2006332185 @default.
• W2080293453 cites W2022306915 @default.
• W2080293453 cites W2022602199 @default.
• W2080293453 cites W2028739120 @default.
• W2080293453 cites W2030742160 @default.
• W2080293453 cites W2031046182 @default.
• W2080293453 cites W2033264916 @default.
• W2080293453 cites W2034213530 @default.
• W2080293453 cites W2036095191 @default.
• W2080293453 cites W2043631520 @default.
• W2080293453 cites W2048856816 @default.
• W2080293453 cites W2053914649 @default.
• W2080293453 cites W2058475680 @default.
• W2080293453 cites W2077875335 @default.
• W2080293453 cites W2079904415 @default.
• W2080293453 cites W2082920447 @default.
• W2080293453 cites W2087783867 @default.
• W2080293453 cites W2091112013 @default.
• W2080293453 cites W2093390983 @default.
• W2080293453 cites W2111498177 @default.
• W2080293453 cites W2129058318 @default.
• W2080293453 cites W2158397444 @default.
• W2080293453 cites W2162420040 @default.
• W2080293453 cites W2949200636 @default.
• W2080293453 cites W2949920351 @default.
• W2080293453 cites W2951797456 @default.
• W2080293453 doi "https://doi.org/10.1016/s1381-1169(00)00240-5" @default.
• W2080293453 hasPublicationYear "2000" @default.
• W2080293453 type Work @default.
• W2080293453 sameAs 2080293453 @default.
• W2080293453 citedByCount "25" @default.
• W2080293453 countsByYear W20802934532012 @default.
• W2080293453 countsByYear W20802934532013 @default.
• W2080293453 countsByYear W20802934532015 @default.
• W2080293453 crossrefType "journal-article" @default.
• W2080293453 hasAuthorship W2080293453A5057431845 @default.
• W2080293453 hasAuthorship W2080293453A5060019697 @default.
• W2080293453 hasConcept C116569031 @default.
• W2080293453 hasConcept C144082473 @default.
• W2080293453 hasConcept C147789679 @default.
• W2080293453 hasConcept C153642686 @default.
• W2080293453 hasConcept C161790260 @default.
• W2080293453 hasConcept C170493617 @default.
• W2080293453 hasConcept C178790620 @default.
• W2080293453 hasConcept C179104552 @default.
• W2080293453 hasConcept C185592680 @default.
• W2080293453 hasConcept C188027245 @default.
• W2080293453 hasConcept C2779240715 @default.
• W2080293453 hasConcept C32909587 @default.
• W2080293453 hasConcept C44228677 @default.
• W2080293453 hasConcept C521977710 @default.
• W2080293453 hasConcept C542268612 @default.
• W2080293453 hasConcept C544153396 @default.
• W2080293453 hasConcept C549387045 @default.
• W2080293453 hasConcept C55493867 @default.
• W2080293453 hasConcept C66974803 @default.
• W2080293453 hasConcept C71240020 @default.
• W2080293453 hasConcept C8010536 @default.
• W2080293453 hasConceptScore W2080293453C116569031 @default.
• W2080293453 hasConceptScore W2080293453C144082473 @default.
• W2080293453 hasConceptScore W2080293453C147789679 @default.
• W2080293453 hasConceptScore W2080293453C153642686 @default.
• W2080293453 hasConceptScore W2080293453C161790260 @default.
• W2080293453 hasConceptScore W2080293453C170493617 @default.
• W2080293453 hasConceptScore W2080293453C178790620 @default.
• W2080293453 hasConceptScore W2080293453C179104552 @default.
• W2080293453 hasConceptScore W2080293453C185592680 @default.
• W2080293453 hasConceptScore W2080293453C188027245 @default.
• W2080293453 hasConceptScore W2080293453C2779240715 @default.
• W2080293453 hasConceptScore W2080293453C32909587 @default.
• W2080293453 hasConceptScore W2080293453C44228677 @default.
• W2080293453 hasConceptScore W2080293453C521977710 @default.
• W2080293453 hasConceptScore W2080293453C542268612 @default.
• W2080293453 hasConceptScore W2080293453C544153396 @default.
• W2080293453 hasConceptScore W2080293453C549387045 @default.
• W2080293453 hasConceptScore W2080293453C55493867 @default.
• W2080293453 hasConceptScore W2080293453C66974803 @default.
• W2080293453 hasConceptScore W2080293453C71240020 @default.
• W2080293453 hasConceptScore W2080293453C8010536 @default.
• W2080293453 hasIssue "1" @default.
• W2080293453 hasLocation W20802934531 @default.
• W2080293453 hasOpenAccess W2080293453 @default.
• W2080293453 hasPrimaryLocation W20802934531 @default.

• next