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- W2080295614 abstract "Abstract Infrared absorption and Raman spectra of 1,2-diiodoethane CH 2 ICH 2 I have been observed in solution and in solid phase, and observed fundamental bands have been assigned. Infrared absorption intensifies have been measured in carbon disulfide solution, and by using the absolute intensity method, the energy difference between the rotational isomers has been obtained as 1·38 ± 0·10 (kcal/mol). It is in quite a good agreement with the value obtained here by using the temperature variation technique. In addition, the normal frequencies and the absolute i.r. absorption intensities have been computed for various assumed dihedral angles for the gauche isomer, and the angle giving the best fit between the observed and computed values has been determined as 85° ± 5°." @default.
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- W2080295614 date "1974-10-01" @default.
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- W2080295614 title "Vibrational frequencies, infrared absorption intensities and energy difference of rotational isomers of 1,2-diiodoethane" @default.
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- W2080295614 doi "https://doi.org/10.1016/0584-8539(74)80037-1" @default.
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