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• W2080302971 abstract "We report resonance-enhanced multiphoton ionization spectra of the isotopologues fluorobenzene-h5 and fluorobenzene-d5. By making use of quantum chemical calculations, the changes in the wavenumber of the vibrational modes upon deuteration are examined. Additionally, the mixing of vibrational modes both between isotopologues and also between the two electronic states is discussed. The isotopic shifts lead to dramatic changes in the appearance of the spectrum as vibrations shift in and out of Fermi resonance. Assignments of the majority of the fluorobenzene-d5 observed bands are provided, aided by previous results on fluorobenzene-h5." @default.
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• W2080302971 date "2014-12-28" @default.
• W2080302971 modified "2023-10-06" @default.
• W2080302971 title "Vibrations of the S1 state of fluorobenzene-<i>h</i>5 and fluorobenzene-<i>d</i>5 via resonance-enhanced multiphoton ionization (REMPI) spectroscopy" @default.
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• W2080302971 doi "https://doi.org/10.1063/1.4904706" @default.
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