FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080304179> ?p ?o ?g. }

• W2080304179 endingPage "4263" @default.
• W2080304179 startingPage "4258" @default.
• W2080304179 abstract "A novel method was developed for synthesizing subnano-sized zero-valent iron (ZVI) using smectite clay layers as templates. Exchangeable Fe(III) cations compensating the structural negative charges of smectites were reduced with NaBH(4), resulting in the formation of ZVI. The unique structure of smectite clay, in which isolated exchangeable Fe(III) cations reside near the sites of structural negative charges, inhibited the agglomeration of ZVI resulting in the formation of subnanoscale ZVI particles in the smectite interlayer regions. X-ray diffraction revealed an interlayer spacing of approximately 5 A. The non-structural iron content of this clay yields a calculated ratio of two atoms of ZVI per three cation exchange sites, in full agreement with the X-ray diffraction (XRD) results since the diameter of elemental Fe is 2.5 A. The clay-templated ZVI showed superior reactivity and efficiency compared to other previously reported forms of ZVI as indicated by the reduction of nitrobenzene; structural Fe within the aluminosilicate layers was nonreactive. At a 1:3 molar ratio of nitrobenzene/non-structural Fe, a reaction efficiency of 83% was achieved, and over 80% of the nitrobenzene was reduced within one minute. These results confirm that non-structural Fe from Fe(III)-smectite was reduced predominantly to ZVI which was responsible for the reduction of nitrobenzene to aniline. This new form of subnanoscale ZVI may find utility in the development of remediation technologies for persistent environmental contaminants, for example, as components of constructed reactive domains such as reactive caps for contaminated sediments." @default.
• W2080304179 created "2016-06-24" @default.
• W2080304179 creator A5030296563 @default.
• W2080304179 creator A5044044684 @default.
• W2080304179 creator A5049822836 @default.
• W2080304179 creator A5058030713 @default.
• W2080304179 creator A5064042293 @default.
• W2080304179 date "2010-05-06" @default.
• W2080304179 modified "2023-10-14" @default.
• W2080304179 title "Synthesis of Highly Reactive Subnano-Sized Zero-Valent Iron Using Smectite Clay Templates" @default.
• W2080304179 cites W1565691667 @default.
• W2080304179 cites W1580906881 @default.
• W2080304179 cites W1964537205 @default.
• W2080304179 cites W1964799795 @default.
• W2080304179 cites W1972311384 @default.
• W2080304179 cites W1974519189 @default.
• W2080304179 cites W1975308807 @default.
• W2080304179 cites W1976733452 @default.
• W2080304179 cites W1977396126 @default.
• W2080304179 cites W1987017467 @default.
• W2080304179 cites W1995346265 @default.
• W2080304179 cites W1995893501 @default.
• W2080304179 cites W1995897201 @default.
• W2080304179 cites W1995933227 @default.
• W2080304179 cites W1999418714 @default.
• W2080304179 cites W2004894585 @default.
• W2080304179 cites W2008424171 @default.
• W2080304179 cites W2010532473 @default.
• W2080304179 cites W2012263367 @default.
• W2080304179 cites W2015210386 @default.
• W2080304179 cites W2016245480 @default.
• W2080304179 cites W2029858442 @default.
• W2080304179 cites W2030840798 @default.
• W2080304179 cites W2035370607 @default.
• W2080304179 cites W2035758570 @default.
• W2080304179 cites W2038357100 @default.
• W2080304179 cites W2041196710 @default.
• W2080304179 cites W2045160502 @default.
• W2080304179 cites W2063498999 @default.
• W2080304179 cites W2064136773 @default.
• W2080304179 cites W2064243824 @default.
• W2080304179 cites W2067729614 @default.
• W2080304179 cites W2068340902 @default.
• W2080304179 cites W2070958087 @default.
• W2080304179 cites W2083162769 @default.
• W2080304179 cites W2088028375 @default.
• W2080304179 cites W2089688447 @default.
• W2080304179 cites W2091129738 @default.
• W2080304179 cites W2091196810 @default.
• W2080304179 cites W2105732889 @default.
• W2080304179 cites W2150586733 @default.
• W2080304179 cites W2161129521 @default.
• W2080304179 cites W2165601178 @default.
• W2080304179 cites W2328340213 @default.
• W2080304179 cites W2949405579 @default.
• W2080304179 doi "https://doi.org/10.1021/es903801r" @default.
• W2080304179 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2892840" @default.
• W2080304179 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20446730" @default.
• W2080304179 hasPublicationYear "2010" @default.
• W2080304179 type Work @default.
• W2080304179 sameAs 2080304179 @default.
• W2080304179 citedByCount "98" @default.
• W2080304179 countsByYear W20803041792012 @default.
• W2080304179 countsByYear W20803041792013 @default.
• W2080304179 countsByYear W20803041792014 @default.
• W2080304179 countsByYear W20803041792015 @default.
• W2080304179 countsByYear W20803041792016 @default.
• W2080304179 countsByYear W20803041792017 @default.
• W2080304179 countsByYear W20803041792018 @default.
• W2080304179 countsByYear W20803041792019 @default.
• W2080304179 countsByYear W20803041792020 @default.
• W2080304179 countsByYear W20803041792021 @default.
• W2080304179 countsByYear W20803041792022 @default.
• W2080304179 countsByYear W20803041792023 @default.
• W2080304179 crossrefType "journal-article" @default.
• W2080304179 hasAuthorship W2080304179A5030296563 @default.
• W2080304179 hasAuthorship W2080304179A5044044684 @default.
• W2080304179 hasAuthorship W2080304179A5049822836 @default.
• W2080304179 hasAuthorship W2080304179A5058030713 @default.
• W2080304179 hasAuthorship W2080304179A5064042293 @default.
• W2080304179 hasBestOaLocation W20803041792 @default.
• W2080304179 hasConcept C127413603 @default.
• W2080304179 hasConcept C142724271 @default.
• W2080304179 hasConcept C147789679 @default.
• W2080304179 hasConcept C150394285 @default.
• W2080304179 hasConcept C161790260 @default.
• W2080304179 hasConcept C178790620 @default.
• W2080304179 hasConcept C179104552 @default.
• W2080304179 hasConcept C185592680 @default.
• W2080304179 hasConcept C199289684 @default.
• W2080304179 hasConcept C204787440 @default.
• W2080304179 hasConcept C2776910235 @default.
• W2080304179 hasConcept C2779244968 @default.
• W2080304179 hasConcept C2780809723 @default.
• W2080304179 hasConcept C2994067411 @default.
• W2080304179 hasConcept C40212044 @default.
• W2080304179 hasConcept C40472508 @default.
• W2080304179 hasConcept C42360764 @default.

• next