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• W2080307346 abstract "An efficient method for the nucleophilic ring opening of stereochemically well-defined aryl pyranosides is described. The reaction effects a formal deoxygenation of the benzylic position to provide useful, enantioenriched building blocks. To illustrate the utility of the Sc(OTf)3-promoted ring opening, a short synthesis of the C11−C21 fragment of reblastatin and geldanamycin is described." @default.
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• W2080307346 date "2006-12-14" @default.
• W2080307346 modified "2023-10-11" @default.
• W2080307346 title "Mild Reductive Opening of Aryl Pyranosides Promoted by Scandium(III) Triflate" @default.
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• W2080307346 doi "https://doi.org/10.1021/ja067234o" @default.
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