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- W2080310295 abstract "Two efficient enantioselective syntheses of an A-ring precursor to 1 α,25-dihydroxyvitamin D3 have been developed. The key step in these sequences involves the stereoselective cyclopropanation of a chiral γ-alkoxy-α-diazo-β-keto ester. In one sequence, the 1 α-hydroxy group was introduced in the first step by a diastereoselective ene reaction and in the other sequence by use of (S)-malic acid as starting material. Both routes eliminate the need for a SeO2 oxidation." @default.
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- W2080310295 date "1995-04-01" @default.
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- W2080310295 title "Stereoselective intramolecular cyclopropanations: Enantioselective syntheses of 1α,25-dihydroxyvitamin D3 A-ring precursors" @default.
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- W2080310295 doi "https://doi.org/10.1016/0040-4039(95)00284-j" @default.
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