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- W2080321481 abstract "The results are presented of an investigation of the high-speed sedimentation of solutions of chitozan fractions with an average degree of deacetylation of 0·8 in 0·33 M CH3COOH and of fractions of chitin nitrate with an average degree of substitution of 1·75 in DMFA. The molecular mass of the fractions, which correlates with MSD. was determined from the value of the characteristics sedimentation coefficient [S] and the concentration parameter ks. The experimental data for chitozan and chitin nitrate can be described, in generalized coordinates, by the same relationships. The equation [S]/Mo = 2·87 × 10−18Z0·37 ± 0.013 was obtained, where Mo is the molecular mass of the repeating unit and Z the degree of polymerization. The fonformational parameters of model molecular chains have been assessed. The length of the Kuhn segment has been found to be A = 23 ± 4·5 nm." @default.
- W2080321481 created "2016-06-24" @default.
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- W2080321481 date "1986-01-01" @default.
- W2080321481 modified "2023-09-26" @default.
- W2080321481 title "High-speed sedimentation, molecular mass and conformational parameters of certain soluble derivatives of chitin" @default.
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- W2080321481 doi "https://doi.org/10.1016/0032-3950(86)90413-2" @default.
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