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- W2080328068 abstract "The complexation of n-heptanal and 4-(n-heptyl)benzaldehyde with TiCl4 was studied spectroscopically. It was observed that the nature of the complex formed was dependent upon the stoichiometry of TiCl4 present. The 2:1 (Lewis base /TiCl4) complex was preferred at sub-stoichiometric quantities of TiCl4 while the 1:1 complex formed preferentially when excess TiCl4 was present. Reaction of the pre-complexed aldehyde with allyltrimethylsilane led to the formation of a titanium alkoxide, the structure of which was independently established by metathesis of the corresponding silyl ether. No metathesis of the allylsilane occurred before addition. The reaction of allyltrimethylsilane with TiCl4-complexed enones was also studied. A titanium enolate was observed spectroscopically as the intermediate in this reaction. No metathesis of the allylsilane occurred before addition to the complexed enone." @default.
- W2080328068 created "2016-06-24" @default.
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- W2080328068 date "1992-07-01" @default.
- W2080328068 modified "2023-09-23" @default.
- W2080328068 title "Spectroscopic studies on the TiCl4-promoted reaction of allylsilanes with aldehydes and α,β-enones" @default.
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- W2080328068 doi "https://doi.org/10.1016/0040-4020(92)80007-3" @default.
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