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- W2080329440 abstract "The stability of 12-heteropolyanions (HPAs) is examined with a novel method, using the rate of exchange of structural units between tungsten and molybdenum HPAs. The Mo/ W exchange is monitored with 31P NMR. The exchange is fast in water, and is influenced by the proton concentration. A mechanism is proposed for the exchange. In organic media no exchange is observed. The results have implications for the catalytic activity of HPAs in different reactions." @default.
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- W2080329440 date "1990-12-01" @default.
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- W2080329440 title "Mo/W interchange of heteropolyanions as a measure of stability: a 31P NMR study" @default.
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- W2080329440 doi "https://doi.org/10.1016/0304-5102(90)85126-3" @default.
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