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- W2080362901 abstract "Abstract The cyclic voltammetric behavior of the (NH3)5 RuL3+/2+, (CN)5FeL2-/3+ and (CN)5RuL2-/3-series of complexes L = an imidazole, a pyrazole or 4-aminopyridine is described in relation to the behavior of various saturated donors (H2O, NH3) and stronger π- acceptor ligands (pyrazine, pyridine). The influence of σ-donation, π-acceptor character and π-donor ability result in E1/2 values that become more positive with increasing π-acceptor character. The influence of σ-donation and π-donation is rather minimal in spite of the marked influence of the properties on the LMCT spectra of the M(III) complexes of the same series and the Mossbauer spectra for (CN)5FeL2- in particular." @default.
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- W2080362901 date "1984-01-01" @default.
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- W2080362901 title "Cyclic Voltammetry of (Cn)5FeL2-/3-and (Nh3)5RuL3+/2+Imidazole and Pyrazole Complexes" @default.
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