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- W2080376145 abstract "Rotationally resolved infrared absorption spectra for the 101 band of jet cooled cobalt tricarbonyl nitrosyl have been observed and analyzed. Several longitudinal modes of a Pb-salt diode laser were utilized to measure 105 rovibrational transitions for this particular vibrational band centered near 2112 cm−1. Spectra were optimized using both argon and helium carrier gases and these experiments eventually led to rovibrational transitions being assigned to four different K subbands, specifically the K=0, 3, 6, and 9 subbands. An iterative least-squares analysis of the spectroscopic data yielded the following molecular parameters ν̃0=2111.7457(9) cm−1, B0=0.034747(12) cm−1, B1=0.034695(15) cm−1, C1=0.03380(9) cm−1, and D1K=6.3(9)×10−6 cm−1 (where 3σ uncertainties are listed in parenthesis)." @default.
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- W2080376145 date "2004-02-24" @default.
- W2080376145 modified "2023-10-17" @default.
- W2080376145 title "Infrared laser spectroscopy of jet cooled cobalt tricarbonyl nitrosyl" @default.
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- W2080376145 doi "https://doi.org/10.1063/1.1643898" @default.
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