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- W2080386331 abstract "The crystal structure of the fluorite-related praseodymium compounds with the composition Pr3MO7, M = Nb, Ta, and Sb, have been determined using Rietveld refinement from X-ray and neutron powder diffraction data at 293 and 4 K. The structure described is orthorhombic with space group Cmcm (No. 63). It is a superstructure of the cubic fluorite structure with unit cell parameters aorth ≈ 2ac, borth ≈ corth ≈ ac2, as in La3NbO7. This structure consists of chains of corner linked MO6 octahedra parallel with the c-axis. The magnetic susceptibility was measured between 4 and 300 K. The compounds obey the Curie-Weiss law including a Van Vleck temperature independent term. Pr3SbO7 shows a small deviation from this law below 25 K." @default.
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- W2080386331 date "1994-01-01" @default.
- W2080386331 modified "2023-10-03" @default.
- W2080386331 title "The Structure and Magnetic Properties of Pr3MO7 with M = Nb, Ta, and Sb" @default.
- W2080386331 doi "https://doi.org/10.1006/jssc.1994.1003" @default.
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