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- W2080395510 abstract "Novel organoboron polymers were prepared by alkoxyboration polymerization of diisocyanates with mesityldimethoxyborane. The polymers obtained have boronic carbamate in their repeating units and can be expected as a novel type of reactive polymers. First, alkoxyboration polymerization between mesityldimethoxyborane and 1,6-hexamethylene diisocyanate was examined, and the best reaction condition was optimized to be 140 °C in bulk. Both aliphatic and aromatic diisocyanates gave the corresponding polymers. When aromatic diisocyanates were employed, the reactions required severe reaction conditions (150 °C). The polymers prepared from aromatic diisocyanates have a high stability toward air. Among various boron monomers, mesityldimethoxyborane was found to be the most suitable monomer for the present polymerization system." @default.
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- W2080395510 date "1998-05-19" @default.
- W2080395510 modified "2023-09-25" @default.
- W2080395510 title "Alkoxyboration Polymerization. Synthesis of Novel Poly(boronic carbamate)s" @default.
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- W2080395510 doi "https://doi.org/10.1021/ma971263p" @default.
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