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• W2080409825 abstract "This study shows that reasonably controlled nitroxide-mediated polymerization of acrylamide is achieved in pure water solution at 120 °C and high concentration (40 wt%), using a combination of a conventional hydrosoluble radical initiator (Vazo56) and a β-phosphonylated nitroxide, SG1. Moreover, some chain extensions can be performed from a polyacrylamide macroinitiator. Under these experimental conditions, we have demonstrated the conservation of the acrylamide structure without hydrolysis side reactions. The physico-chemical characterizations of polymers obtained from this method demonstrates that the controlled growing chain arises as a star-like shape from the hydrophobic core composed of SG1-functionalized polyacrylamide in the presence of a slight excess of SG1." @default.
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• W2080409825 date "2008-01-01" @default.
• W2080409825 modified "2023-10-18" @default.
• W2080409825 title "Nitroxide-mediated radical polymerization of acrylamide in water solution" @default.
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• W2080409825 doi "https://doi.org/10.1016/j.eurpolymj.2007.10.019" @default.
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