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• W2080420596 abstract "We develop an eikonal treatment of electronic transitions in many‐atom collisions, in which classical nuclear trajectories are self‐consistently coupled to quantal electronic transitions. The treatment starts with a discussion of the electronic representations required to assure that Hamiltonian matrices are Hermitian. The amplitudes of wave functions are found to satisfy coupled equations which are expanded in powers of a local de Broglie wavelength. Time‐dependent equations are transformed to derive a Hamiltonian formalism that couples nuclear positions and momenta with electronic amplitudes. Cross sections are obtained from flux conservation and also from T‐matrix elements." @default.
• W2080420596 created "2016-06-24" @default.
• W2080420596 creator A5036764900 @default.
• W2080420596 date "1983-06-15" @default.
• W2080420596 modified "2023-09-27" @default.
• W2080420596 title "A self‐consistent eikonal treatment of electronic transitions in molecular collisions" @default.
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• W2080420596 doi "https://doi.org/10.1063/1.444753" @default.
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