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- W2080440566 abstract "According to the crystallographic investigation of single crystals of four members of the chiral complex series [Ln(η5-C5H5)2-μ-(R)-(−)-OCH2CH(Et)NMe2]2 (Ln=Nd, Sm, Tb, Y)1 the existence of dinuclear molecules with almost symmetrical {Ln2(μ-OCH2)2} cores, but two notably different LnN separations (Δ(LnN)=0.235–0.357 Å) has been established. The formation of two non-equivalent {Ln(C5H5)2OR} fragments could independently be demonstrated by multinuclear (13C, 15N, 89Y) CPMAS solid-state NMR studies of the complex with Ln=Y. In contrast, solution-state NMR spectra (1H, 13C, 89Y) including, moreover, those of the homologues with Ln=La and Tm are consistent with virtually higher molecular symmetries (i.e. at least of C2 symmetry) even at comparatively low temperatures. While, owing to the presence of chirogenic centres, the insight into structural details is improved, the overall molecular structure of the title complexes becomes slightly more complicated." @default.
- W2080440566 created "2016-06-24" @default.
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- W2080440566 date "2003-07-01" @default.
- W2080440566 modified "2023-09-24" @default.
- W2080440566 title "Unusually structured organolanthanoid(III) dimers with two chiral, but not strictly equivalent, nitrogen-functionalized alkoxide bridges" @default.
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- W2080440566 doi "https://doi.org/10.1016/s0010-8545(03)00025-0" @default.
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