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- W2080443003 abstract "The crystal structure of racemic cis-C2-anti-[oxalatobis(2R,4S-diaminopentane)cobat(III)] perchlorate has been determined by diffractometric methods. The salt crystallizes in the triclinic space group P1, with unit cell constants a = 11.005(3), b = 11.863(3), c = 7626(2) Å, α = 103.36(1), β = 90. O9(1), and γ = 74.00(1)°, and Z = 2. Full-matrix least-squares refinement on F utilizing 3478 reflections with F?? >> 3σ(F2o) converged at a conventional agreement factor of 0.052. The inner sphere coordination geometry of the cobalt atom is octahedral, and the cation possesses pseudo C2 symmetry. The 2,4-diaminopentane rings adopt the chair conformation. The perchlorate ion is disordered and has been refined as two rigid, tetrahedral groups." @default.
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- W2080443003 date "1978-01-01" @default.
- W2080443003 modified "2023-09-23" @default.
- W2080443003 title "Complexes of meso bidentate ligands. The crystal structure of the racemic modification of cis-C2-anti-[oxalatobis(2R,4S-diaminopentane)cobalt(III)] perchlorate" @default.
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- W2080443003 doi "https://doi.org/10.1016/s0020-1693(00)89041-6" @default.
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