Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080453775> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2080453775 endingPage "17185" @default.
- W2080453775 startingPage "17175" @default.
- W2080453775 abstract "We describe a model of the Briggs−Rauscher reaction closely related to those due to Furrow and Noyes and to DeKepper and Epstein. The model has been fitted to 16 experimental basic quenching parameters at a Hopf bifurcation point. The fit is quite good. Predictions of the model are compared with experiments close to the Hopf bifurcation as well as at several operating points away from it and with experiments under batch conditions. The angular frequency of the finite limit cycle oscillations near the Hopf bifurcation is half the value observed in the experiments. The relative phases of the concentration oscillations of O2 and I- agree reasonably well with the experiments, but the average values are 1 or 2 orders of magnitude smaller in the simulations. The model demonstrates that it is possible to account for a paradoxical behavior of perturbation by OH- as compared to that of H+ and that quenching from a finite limit cycle may be impossible to realize. It qualitatively explains four distinct quenching experiments by dilution. At three separate operation points away from the Hopf bifurcation the model reproduces two observed patterns, namely, one of bistability between a stationary state and a limit cycle and one of mixed mode oscillations, but it fails to reproduce observed burst oscillations at the appropriate point. The model can reproduce transient batch mode oscillations and other transient behavior. The model of Furrow and Noyes with a more recent set of rate constants and a reduced version of it, derived by sensitivity analysis, are also compared with experiments." @default.
- W2080453775 created "2016-06-24" @default.
- W2080453775 creator A5023579543 @default.
- W2080453775 creator A5060401993 @default.
- W2080453775 creator A5064531749 @default.
- W2080453775 date "1996-01-01" @default.
- W2080453775 modified "2023-09-29" @default.
- W2080453775 title "Predictive Value of a Model of the Briggs−Rauscher Reaction Fitted to Quenching Experiments" @default.
- W2080453775 cites W2001545854 @default.
- W2080453775 cites W2014490356 @default.
- W2080453775 cites W2028857802 @default.
- W2080453775 cites W2034259409 @default.
- W2080453775 cites W2060355323 @default.
- W2080453775 cites W2065599603 @default.
- W2080453775 cites W2067917338 @default.
- W2080453775 cites W2068855277 @default.
- W2080453775 cites W2073120349 @default.
- W2080453775 cites W2077443667 @default.
- W2080453775 cites W2078101387 @default.
- W2080453775 cites W2082503027 @default.
- W2080453775 cites W2095296680 @default.
- W2080453775 cites W2129032765 @default.
- W2080453775 doi "https://doi.org/10.1021/jp960785o" @default.
- W2080453775 hasPublicationYear "1996" @default.
- W2080453775 type Work @default.
- W2080453775 sameAs 2080453775 @default.
- W2080453775 citedByCount "45" @default.
- W2080453775 countsByYear W20804537752012 @default.
- W2080453775 countsByYear W20804537752014 @default.
- W2080453775 countsByYear W20804537752016 @default.
- W2080453775 countsByYear W20804537752017 @default.
- W2080453775 countsByYear W20804537752018 @default.
- W2080453775 countsByYear W20804537752019 @default.
- W2080453775 countsByYear W20804537752021 @default.
- W2080453775 countsByYear W20804537752022 @default.
- W2080453775 crossrefType "journal-article" @default.
- W2080453775 hasAuthorship W2080453775A5023579543 @default.
- W2080453775 hasAuthorship W2080453775A5060401993 @default.
- W2080453775 hasAuthorship W2080453775A5064531749 @default.
- W2080453775 hasConcept C121332964 @default.
- W2080453775 hasConcept C121745418 @default.
- W2080453775 hasConcept C134306372 @default.
- W2080453775 hasConcept C151201525 @default.
- W2080453775 hasConcept C158622935 @default.
- W2080453775 hasConcept C172435161 @default.
- W2080453775 hasConcept C185592680 @default.
- W2080453775 hasConcept C2781349735 @default.
- W2080453775 hasConcept C33923547 @default.
- W2080453775 hasConcept C57879066 @default.
- W2080453775 hasConcept C62520636 @default.
- W2080453775 hasConcept C85075877 @default.
- W2080453775 hasConcept C91881484 @default.
- W2080453775 hasConcept C93357160 @default.
- W2080453775 hasConcept C96618451 @default.
- W2080453775 hasConcept C97292510 @default.
- W2080453775 hasConcept C97355855 @default.
- W2080453775 hasConceptScore W2080453775C121332964 @default.
- W2080453775 hasConceptScore W2080453775C121745418 @default.
- W2080453775 hasConceptScore W2080453775C134306372 @default.
- W2080453775 hasConceptScore W2080453775C151201525 @default.
- W2080453775 hasConceptScore W2080453775C158622935 @default.
- W2080453775 hasConceptScore W2080453775C172435161 @default.
- W2080453775 hasConceptScore W2080453775C185592680 @default.
- W2080453775 hasConceptScore W2080453775C2781349735 @default.
- W2080453775 hasConceptScore W2080453775C33923547 @default.
- W2080453775 hasConceptScore W2080453775C57879066 @default.
- W2080453775 hasConceptScore W2080453775C62520636 @default.
- W2080453775 hasConceptScore W2080453775C85075877 @default.
- W2080453775 hasConceptScore W2080453775C91881484 @default.
- W2080453775 hasConceptScore W2080453775C93357160 @default.
- W2080453775 hasConceptScore W2080453775C96618451 @default.
- W2080453775 hasConceptScore W2080453775C97292510 @default.
- W2080453775 hasConceptScore W2080453775C97355855 @default.
- W2080453775 hasIssue "43" @default.
- W2080453775 hasLocation W20804537751 @default.
- W2080453775 hasOpenAccess W2080453775 @default.
- W2080453775 hasPrimaryLocation W20804537751 @default.
- W2080453775 hasRelatedWork W1876558431 @default.
- W2080453775 hasRelatedWork W2018197389 @default.
- W2080453775 hasRelatedWork W2128548899 @default.
- W2080453775 hasRelatedWork W2144554174 @default.
- W2080453775 hasRelatedWork W2262919813 @default.
- W2080453775 hasRelatedWork W2340824690 @default.
- W2080453775 hasRelatedWork W2378176293 @default.
- W2080453775 hasRelatedWork W2382044318 @default.
- W2080453775 hasRelatedWork W2555766691 @default.
- W2080453775 hasRelatedWork W4312231517 @default.
- W2080453775 hasVolume "100" @default.
- W2080453775 isParatext "false" @default.
- W2080453775 isRetracted "false" @default.
- W2080453775 magId "2080453775" @default.
- W2080453775 workType "article" @default.