FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080458648> ?p ?o ?g. }

• W2080458648 endingPage "37" @default.
• W2080458648 startingPage "34" @default.
• W2080458648 abstract "In classical volcano correlations in electrocatalysis, the shape of (log io) plots versus the binding energy of the reactant to active sites, the maximum activity is associated to a situation where the surface coverage of reactant species is equal to 0.5 corresponding to a free energy of adsorption of the reactant equal to zero. When studying electrochemical reactions catalysed by macrocyclic transition metal complexes adsorbed on graphite electrodes, volcano correlations are found when plotting the activity versus the formal potential of the catalyst for several reactions, assuming that the formal potential is somehow related to the free energy of the adsorption of the reacting molecule. In this work we offer an interpretation different from that given in the literature for these correlations for the electrooxidation of hydrazine. The highest catalytic activity is achieved when the formal potential of the catalyst approaches the N2H4/N2 reversible potential. In contrast, if log i (normalized for the actual surface concentrations of Fe(II) active sites at constant potential) is plotted versus the difference between the Fe(II)/(I) formal potential of the catalysts and the standard potential of the N2H4/N2 reaction, the correlation is linear with a slope close to 2RT/F." @default.
• W2080458648 created "2016-06-24" @default.
• W2080458648 creator A5014552784 @default.
• W2080458648 creator A5024843615 @default.
• W2080458648 creator A5030489335 @default.
• W2080458648 creator A5043992472 @default.
• W2080458648 creator A5083673263 @default.
• W2080458648 date "2013-05-01" @default.
• W2080458648 modified "2023-10-02" @default.
• W2080458648 title "Tuning the Fe(II)/(I) formal potential of the FeN4 catalysts adsorbed on graphite electrodes to the reversible potential of the reaction for maximum activity: Hydrazine oxidation" @default.
• W2080458648 cites W1966864166 @default.
• W2080458648 cites W1971842594 @default.
• W2080458648 cites W1973582590 @default.
• W2080458648 cites W1993583725 @default.
• W2080458648 cites W2006300638 @default.
• W2080458648 cites W2022714449 @default.
• W2080458648 cites W2023106039 @default.
• W2080458648 cites W2042254924 @default.
• W2080458648 cites W2055561490 @default.
• W2080458648 cites W2062623195 @default.
• W2080458648 cites W2063241979 @default.
• W2080458648 cites W2063794595 @default.
• W2080458648 cites W2066952153 @default.
• W2080458648 cites W2069177886 @default.
• W2080458648 cites W2073867476 @default.
• W2080458648 cites W2082498072 @default.
• W2080458648 cites W2094166953 @default.
• W2080458648 cites W2102333114 @default.
• W2080458648 cites W2135923395 @default.
• W2080458648 cites W2139140308 @default.
• W2080458648 cites W2328528050 @default.
• W2080458648 doi "https://doi.org/10.1016/j.elecom.2013.01.024" @default.
• W2080458648 hasPublicationYear "2013" @default.
• W2080458648 type Work @default.
• W2080458648 sameAs 2080458648 @default.
• W2080458648 citedByCount "27" @default.
• W2080458648 countsByYear W20804586482014 @default.
• W2080458648 countsByYear W20804586482015 @default.
• W2080458648 countsByYear W20804586482016 @default.
• W2080458648 countsByYear W20804586482017 @default.
• W2080458648 countsByYear W20804586482019 @default.
• W2080458648 countsByYear W20804586482020 @default.
• W2080458648 countsByYear W20804586482021 @default.
• W2080458648 countsByYear W20804586482022 @default.
• W2080458648 crossrefType "journal-article" @default.
• W2080458648 hasAuthorship W2080458648A5014552784 @default.
• W2080458648 hasAuthorship W2080458648A5024843615 @default.
• W2080458648 hasAuthorship W2080458648A5030489335 @default.
• W2080458648 hasAuthorship W2080458648A5043992472 @default.
• W2080458648 hasAuthorship W2080458648A5083673263 @default.
• W2080458648 hasConcept C106773901 @default.
• W2080458648 hasConcept C125086356 @default.
• W2080458648 hasConcept C147789679 @default.
• W2080458648 hasConcept C150394285 @default.
• W2080458648 hasConcept C161790260 @default.
• W2080458648 hasConcept C17525397 @default.
• W2080458648 hasConcept C178790620 @default.
• W2080458648 hasConcept C179104552 @default.
• W2080458648 hasConcept C185592680 @default.
• W2080458648 hasConcept C18787249 @default.
• W2080458648 hasConcept C2776597398 @default.
• W2080458648 hasConcept C2779698641 @default.
• W2080458648 hasConcept C32909587 @default.
• W2080458648 hasConcept C33989665 @default.
• W2080458648 hasConcept C43617362 @default.
• W2080458648 hasConcept C52859227 @default.
• W2080458648 hasConcept C544153396 @default.
• W2080458648 hasConcept C65024703 @default.
• W2080458648 hasConceptScore W2080458648C106773901 @default.
• W2080458648 hasConceptScore W2080458648C125086356 @default.
• W2080458648 hasConceptScore W2080458648C147789679 @default.
• W2080458648 hasConceptScore W2080458648C150394285 @default.
• W2080458648 hasConceptScore W2080458648C161790260 @default.
• W2080458648 hasConceptScore W2080458648C17525397 @default.
• W2080458648 hasConceptScore W2080458648C178790620 @default.
• W2080458648 hasConceptScore W2080458648C179104552 @default.
• W2080458648 hasConceptScore W2080458648C185592680 @default.
• W2080458648 hasConceptScore W2080458648C18787249 @default.
• W2080458648 hasConceptScore W2080458648C2776597398 @default.
• W2080458648 hasConceptScore W2080458648C2779698641 @default.
• W2080458648 hasConceptScore W2080458648C32909587 @default.
• W2080458648 hasConceptScore W2080458648C33989665 @default.
• W2080458648 hasConceptScore W2080458648C43617362 @default.
• W2080458648 hasConceptScore W2080458648C52859227 @default.
• W2080458648 hasConceptScore W2080458648C544153396 @default.
• W2080458648 hasConceptScore W2080458648C65024703 @default.
• W2080458648 hasLocation W20804586481 @default.
• W2080458648 hasOpenAccess W2080458648 @default.
• W2080458648 hasPrimaryLocation W20804586481 @default.
• W2080458648 hasRelatedWork W1027273287 @default.
• W2080458648 hasRelatedWork W166146962 @default.
• W2080458648 hasRelatedWork W1978215426 @default.
• W2080458648 hasRelatedWork W1994052679 @default.
• W2080458648 hasRelatedWork W1999602177 @default.
• W2080458648 hasRelatedWork W2028794953 @default.
• W2080458648 hasRelatedWork W2139865980 @default.
• W2080458648 hasRelatedWork W2161787500 @default.
• W2080458648 hasRelatedWork W2352206413 @default.

• next