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• W2080458838 abstract "Photon-correlation spectroscopy has been used to measure the diffusion coefficient D and first-mode intramolecular relaxation time τ1 of polystyrene in a theta solvent, cyclohexane at 34.5°C. Measurements were made on five narrow fractions (Mw = 2.88 × 106 to 9.35 × 106) as a function of concentration c, in the dilute regime. D varied linearly with c, D = Do (I + kDc), with Do = (1.4 ± 0.2) × 10−4 Mw−(0.508±0.007) cm2 s−1. Although the values obtained for τ1 were reproducible to within 5%, no systematic variation with c was detected. The results are fitted by the relation τ1 = (7.7 ∓ 0.3) × 10−8 Mw(1.42±0.05) μs, which agrees well with the theoretical expression of Zimm for the non-draining bead-and-spring model, modified for the light-scattering case." @default.
• W2080458838 created "2016-06-24" @default.
• W2080458838 creator A5062051968 @default.
• W2080458838 creator A5006838187 @default.
• W2080458838 date "1979-03-01" @default.
• W2080458838 modified "2023-10-17" @default.
• W2080458838 title "Intramolecular relaxation of polystyrene in a theta solvent by photon-correlation spectroscopy" @default.
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• W2080458838 doi "https://doi.org/10.1016/0301-0104(79)80018-x" @default.
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