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• W2080461809 abstract "An atom-economical synthesis of chiral polyfunctionalized spiropyrazolone derivatives based on the development of a new organocatalytic enantioselective one-pot sequential Michael/Michael/Aldol reaction of 1,3-dicarbonyl compounds with unsaturated pyrazolones and α,β-unsaturated aldehydes has been developed. The notable features of this one-pot sequential process include the generation of up to six consecutive stereogenic carbon centers including one quaternary stereocenter and five tertiary stereocenters with high enantioselectivities (up to 95% ee) and excellent diastereoselectivities (>99:1 d.r.)." @default.
• W2080461809 created "2016-06-24" @default.
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• W2080461809 date "2014-12-01" @default.
• W2080461809 modified "2023-09-25" @default.
• W2080461809 title "Organocatalytic asymmetric one-pot sequential reaction: synthesis of highly substituted spirocyclohexanepyrazolones with six contiguous stereogenic carbons" @default.
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• W2080461809 doi "https://doi.org/10.1016/j.tet.2014.10.038" @default.
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