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• W2080462566 abstract "We demonstrate the ability of first row transition metals to form electrically conducting interconnects between semiconducting single-walled carbon nanotubes (SWNTs) by constructive rehybridization between sidewall benzene rings as a result of the formation of bis-hexahapto-metal-bonds [(η6-SWNT)M(η6-SWNT)], which bridge adjacent SWNTs. Metal deposition on SWNT films enhances the conductivity by three distinct mechanisms: physisorption of gold leads to the formation of a non-interacting gold film and a monotonic conductivity increase; ionic chemisorption of lithium strongly increases the conductivity due to charge transfer to the SWNTs; covalent chemisorption of first row transition metals leads to an abrupt change in conductivity due to formation of (η6-SWNT)M(η6-SWNT) interconnects." @default.
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• W2080462566 date "2012-05-28" @default.
• W2080462566 modified "2023-10-16" @default.
• W2080462566 title "Effect of first row transition metals on the conductivity of semiconducting single-walled carbon nanotube networks" @default.
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• W2080462566 doi "https://doi.org/10.1063/1.4723717" @default.
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