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- W2080472964 abstract "Abstract The phase diagrams of the systems LiBr-MgBr; and LiBr-MnBr; have been studied by high temperature X-ray powder diffraction and differential scanning calorimetry measurements. At elevated temperatures, complete series of solid solutions between NaCl-type LiBr and CdCl 2 -type MBr 2 are formed. On cooling to ambient temperature, these solid solutions decompose to LiBr, CdI 2 -type MBr 2 , and the ternary compounds Li 6 MBr 8 (Suzuki type) and Li 2 MBr 4 (SnMn 2 S 4 type). The structures of the ternary bromides can be characterized by different ordering schemes of the metal ions and vacancies on the octahedral sites of the cubic close-packed bromide ions. The symmetry relations to the aristotype NaCl structure and the Coulomb parts of the cohesive energies are given." @default.
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- W2080472964 date "1993-02-01" @default.
- W2080472964 modified "2023-09-26" @default.
- W2080472964 title "Rock-salt defect structures in the systems LiBr-MBr2 (where M is Mg, Mn)" @default.
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- W2080472964 doi "https://doi.org/10.1016/0040-6031(93)80095-r" @default.
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