FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080481116> ?p ?o ?g. }

• W2080481116 endingPage "9401" @default.
• W2080481116 startingPage "9393" @default.
• W2080481116 abstract "The complex [Fe{HC(3-Mepz)2(5-Mepz)}2](BF4)2 (pz = pyrazolyl ring) has been prepared by the reaction of HC(3-Mepz)2(5-Mepz) with Fe(BF4)2·6H2O. The solid state structures obtained at 294 and 150 K show a distorted iron(II) octahedral N6 coordination environment with the largest deviations arising from the restrictions imposed by the chelate rings. At 294 K the complex is predominately high-spin with Fe−N bond distances averaging 2.14 Å, distances that are somewhat shorter than expected for a purely high-spin iron(II) complex because of the presence of an admixture of about 80% high-spin and 20% low-spin iron(II). At 294 K the twisting of the pyrazolyl rings from the ideal C3v symmetry averages only 2.2°, a much smaller twist than has been observed previously in similar complexes. At 150 K the Fe−N bond distances average 1.99 Å, indicative of an almost fully low-spin iron(II) complex; the twist angle is only 1.3°, as expected for a complex with these Fe−N bond distances. The magnetic properties show that the complex undergoes a gradual change from low-spin iron(II) below 85 K to high-spin iron(II) at 400 K. The 4.2 to 60 K Mössbauer spectra correspond to a fully low-spin iron(II) complex but, upon further warming above 85 K, the iron(II) begins to undergo spin-state relaxation between the low- and high-spin forms on the Mössbauer time scale. At 155 and 315 K the complex exhibits spin-state relaxation rates of 0.36 and 7.38 MHz, respectively, and an Arrhenius plot of the logarithm of the relaxation rate yields an activation energy of 670 ± 40 cm−1 for the spin-state relaxation." @default.
• W2080481116 created "2016-06-24" @default.
• W2080481116 creator A5006758709 @default.
• W2080481116 creator A5034938361 @default.
• W2080481116 creator A5041241032 @default.
• W2080481116 creator A5048868175 @default.
• W2080481116 creator A5056066019 @default.
• W2080481116 creator A5070002962 @default.
• W2080481116 date "2009-09-10" @default.
• W2080481116 modified "2023-09-25" @default.
• W2080481116 title "Structural, Magnetic, and Mössbauer Spectral Study of the Electronic Spin-State Transition in [Fe{HC(3-Mepz)₂(5-Mepz)}₂](BF₄)₂" @default.
• W2080481116 cites W1937416178 @default.
• W2080481116 cites W1968101114 @default.
• W2080481116 cites W1993661262 @default.
• W2080481116 cites W2000973114 @default.
• W2080481116 cites W2006291250 @default.
• W2080481116 cites W2010749749 @default.
• W2080481116 cites W2028572274 @default.
• W2080481116 cites W2028785018 @default.
• W2080481116 cites W2033211982 @default.
• W2080481116 cites W2034991501 @default.
• W2080481116 cites W2040221291 @default.
• W2080481116 cites W2041498700 @default.
• W2080481116 cites W2055382992 @default.
• W2080481116 cites W2055590376 @default.
• W2080481116 cites W2057949119 @default.
• W2080481116 cites W2060261232 @default.
• W2080481116 cites W2061061329 @default.
• W2080481116 cites W2061842942 @default.
• W2080481116 cites W2067502608 @default.
• W2080481116 cites W2068070596 @default.
• W2080481116 cites W2074514832 @default.
• W2080481116 cites W2075655227 @default.
• W2080481116 cites W2076833293 @default.
• W2080481116 cites W2079620363 @default.
• W2080481116 cites W2079852306 @default.
• W2080481116 cites W2085823060 @default.
• W2080481116 cites W2092237178 @default.
• W2080481116 cites W2093969145 @default.
• W2080481116 cites W2120985572 @default.
• W2080481116 cites W2141627964 @default.
• W2080481116 cites W2143753629 @default.
• W2080481116 cites W2324425784 @default.
• W2080481116 doi "https://doi.org/10.1021/ic901259e" @default.
• W2080481116 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19780620" @default.
• W2080481116 hasPublicationYear "2009" @default.
• W2080481116 type Work @default.
• W2080481116 sameAs 2080481116 @default.
• W2080481116 citedByCount "14" @default.
• W2080481116 countsByYear W20804811162012 @default.
• W2080481116 countsByYear W20804811162013 @default.
• W2080481116 countsByYear W20804811162014 @default.
• W2080481116 countsByYear W20804811162016 @default.
• W2080481116 countsByYear W20804811162017 @default.
• W2080481116 countsByYear W20804811162019 @default.
• W2080481116 countsByYear W20804811162021 @default.
• W2080481116 crossrefType "journal-article" @default.
• W2080481116 hasAuthorship W2080481116A5006758709 @default.
• W2080481116 hasAuthorship W2080481116A5034938361 @default.
• W2080481116 hasAuthorship W2080481116A5041241032 @default.
• W2080481116 hasAuthorship W2080481116A5048868175 @default.
• W2080481116 hasAuthorship W2080481116A5056066019 @default.
• W2080481116 hasAuthorship W2080481116A5070002962 @default.
• W2080481116 hasConcept C115624301 @default.
• W2080481116 hasConcept C121332964 @default.
• W2080481116 hasConcept C155860418 @default.
• W2080481116 hasConcept C178790620 @default.
• W2080481116 hasConcept C179104552 @default.
• W2080481116 hasConcept C185592680 @default.
• W2080481116 hasConcept C193547582 @default.
• W2080481116 hasConcept C198819137 @default.
• W2080481116 hasConcept C26873012 @default.
• W2080481116 hasConcept C2777222292 @default.
• W2080481116 hasConcept C2778696020 @default.
• W2080481116 hasConcept C32909587 @default.
• W2080481116 hasConcept C35325081 @default.
• W2080481116 hasConcept C42704618 @default.
• W2080481116 hasConcept C70854507 @default.
• W2080481116 hasConcept C8010536 @default.
• W2080481116 hasConcept C97355855 @default.
• W2080481116 hasConceptScore W2080481116C115624301 @default.
• W2080481116 hasConceptScore W2080481116C121332964 @default.
• W2080481116 hasConceptScore W2080481116C155860418 @default.
• W2080481116 hasConceptScore W2080481116C178790620 @default.
• W2080481116 hasConceptScore W2080481116C179104552 @default.
• W2080481116 hasConceptScore W2080481116C185592680 @default.
• W2080481116 hasConceptScore W2080481116C193547582 @default.
• W2080481116 hasConceptScore W2080481116C198819137 @default.
• W2080481116 hasConceptScore W2080481116C26873012 @default.
• W2080481116 hasConceptScore W2080481116C2777222292 @default.
• W2080481116 hasConceptScore W2080481116C2778696020 @default.
• W2080481116 hasConceptScore W2080481116C32909587 @default.
• W2080481116 hasConceptScore W2080481116C35325081 @default.
• W2080481116 hasConceptScore W2080481116C42704618 @default.
• W2080481116 hasConceptScore W2080481116C70854507 @default.
• W2080481116 hasConceptScore W2080481116C8010536 @default.
• W2080481116 hasConceptScore W2080481116C97355855 @default.
• W2080481116 hasIssue "19" @default.

• next